Idioma: Inglés
Publicado por Kluwer Academic Publishers, Norwell, MA, U.S.A., 1988
ISBN 10: 0792300327 ISBN 13: 9780792300328
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Añadir al carritoTaschenbuch. Condición: Neu. Druck auf Anfrage Neuware - Printed after ordering - When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, 'Inorganic Chemistry', Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,'Advanced Organic Chemistry', J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, 'Advanced Inorganic Chemistry', Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, 'Principles and Applications of Organotransition Metal Chemistry', University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenomena. These comparisons show unambiguously that the importance of paramagnetic species in chemical reactivity still lacks a consistent treatment transcending the artificial barriers between branches of Chemistry. This book, which brings together experimental facts and concepts originating from organometallic and organic reactivities, is a step in the direction of bridging this gap. The unifying thread which connects the 35 chapters throughout this book is Activation/Selectivity and Catalysis by means of radical chemistry.
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Idioma: Inglés
Publicado por Springer Netherlands, Springer Okt 2011, 2011
ISBN 10: 9401068828 ISBN 13: 9789401068826
Librería: BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, Alemania
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Añadir al carritoTaschenbuch. Condición: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, 'Inorganic Chemistry', Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,'Advanced Organic Chemistry', J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, 'Advanced Inorganic Chemistry', Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, 'Principles and Applications of Organotransition Metal Chemistry', University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenomena. These comparisons show unambiguously that the importance of paramagnetic species in chemical reactivity still lacks a consistent treatment transcending the artificial barriers between branches of Chemistry. This book, which brings together experimental facts and concepts originating from organometallic and organic reactivities, is a step in the direction of bridging this gap. The unifying thread which connects the 35 chapters throughout this book is Activation/Selectivity and Catalysis by means of radical chemistry. 600 pp. Englisch.
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Añadir al carritoCondición: New. PRINT ON DEMAND pp. 600.
Idioma: Inglés
Publicado por Springer Netherlands, Routledge Okt 2011, 2011
ISBN 10: 9401068828 ISBN 13: 9789401068826
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Añadir al carritoTaschenbuch. Condición: Neu. This item is printed on demand - Print on Demand Titel. Neuware -When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, 'Inorganic Chemistry', Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,'Advanced Organic Chemistry', J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, 'Advanced Inorganic Chemistry', Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, 'Principles and Applications of Organotransition Metal Chemistry', University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenomena. These comparisons show unambiguously that the importance of paramagnetic species in chemical reactivity still lacks a consistent treatment transcending the artificial barriers between branches of Chemistry. This book, which brings together experimental facts and concepts originating from organometallic and organic reactivities, is a step in the direction of bridging this gap. The unifying thread which connects the 35 chapters throughout this book is Activation/Selectivity and Catalysis by means of radical chemistry.Springer-Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 600 pp. Englisch.
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Añadir al carritoTaschenbuch. Condición: Neu. Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis | Michel Chanon (u. a.) | Taschenbuch | 596 S. | Englisch | 2011 | Routledge | EAN 9789401068826 | Verantwortliche Person für die EU: Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg, juergen[dot]hartmann[at]springer[dot]com | Anbieter: preigu Print on Demand.