9780792331070 - theoretical aspects of homogeneous catalysis: applications of ab initio molecular orbital theory: 18 (catalysis by metal complexes, 18) (15 resultados)
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Theoretical Aspects of Homogeneous Catalysis
van Leeuwen, Piet W.N.M., Keiji Morokuma, and Joop H. van Lenthe, editors
Idioma: Inglés
Editorial: Kluwer Academic Publishers, Dordrecht and Boston, 1995
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Condición: New. pp. 232.
Theoretical Aspects of Homogeneous Catalysis
. Ed(s): Leeuwen, P. W. N. M. van; Morokuma, Keiji C.L. (Emerson Center, Emory University, Atlanta, USA); Lenthe, Joop H. Van (Theoretical Chemistry
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Condición: New. Presents the quantitative application of quantum chemistry to organometallic reactions. This title deals with key reactions of homogeneous catalysis including oxidative addition, migratory insertions, 2+2 additions, the Wacker reaction, and epoxidation. It provides experimental chemists with an overview of the st…ate of the art in this field. Editor(s): Leeuwen, P. W. N. M. van; Morokuma, Keiji C.L. (Emerson Center, Emory University, Atlanta, USA); Lenthe, Joop H. Van (Theoretical Chemistry Group, University of Utrecht, Netherlands). Series: Catalysis by Metal Complexes. Num Pages: 220 pages, biography. BIC Classification: PNND; PNRD. Category: (P) Professional & Vocational; (UP) Postgraduate, Research & Scholarly. Dimension: 229 x 152 x 14. Weight in Grams: 504. . 1995. Hardback. . . . .
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Buch. Condición: Neu. Druck auf Anfrage Neuware - Printed after ordering - Homogeneous catalysis plays an important role both in the laboratory and in the industry. Successful applications in industry involve new polymerisation processes with complexes of zirconium and related metals, new carbonylation processes employing pallad…ium and rhodium, ring opening polymerisations, and new enantioselective isomerisation catalysts as in the preparation of menthol. Also in the synthesis of organic compounds in the laboratory highly selective homogeneous catalysts represent an irreplaceable part of the toolbox of the synthetic chemist. Examples of such reactions are cross-coupling (Ni, Pd), nucleophilic substitution of allylpalladium complexes, Heck reactions (Pd), asymmetric epoxidation, Wacker type reactions (Pd), asymmetric hydrogenations (Rh, Ru), reactions of chromium complexes, enantioselective reactions with Lewis acids, reactions with the McMurry reagent, etc. There is hardly any multistep organic synthesis that does not involve one of these metal catalysed reactions. Most of these catalysts have been developed by empiricism. The metal catalysed processes consist of a series of elementary steps which often have been studied in isolation in organometallic chemistry. The knowl edge of such elementary steps - effect ofligands, anions, coordination number, valence states - has greatly contributed to the development of improved cata lysts for the reactions mentioned above. In addition to the empirical approach theoretical methods have given support and guidance to the development of improved processes. Often the key steps of a cycle escape from a direct ob servation and then theoretical contributions are even more wanted.
Theoretical Aspects of Homogeneous Catalysis
. Ed(s): Leeuwen, P. W. N. M. van; Morokuma, Keiji C.L. (Emerson Center, Emory University, Atlanta, USA); Lenthe, Joop H. Van (Theoretical Chemistry
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Condición: New. Presents the quantitative application of quantum chemistry to organometallic reactions. This title deals with key reactions of homogeneous catalysis including oxidative addition, migratory insertions, 2+2 additions, the Wacker reaction, and epoxidation. It provides experimental chemists with an overview of the st…ate of the art in this field. Editor(s): Leeuwen, P. W. N. M. van; Morokuma, Keiji C.L. (Emerson Center, Emory University, Atlanta, USA); Lenthe, Joop H. Van (Theoretical Chemistry Group, University of Utrecht, Netherlands). Series: Catalysis by Metal Complexes. Num Pages: 220 pages, biography. BIC Classification: PNND; PNRD. Category: (P) Professional & Vocational; (UP) Postgraduate, Research & Scholarly. Dimension: 229 x 152 x 14. Weight in Grams: 504. . 1995. Hardback. . . . . Books ship from the US and Ireland.
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Buch. Condición: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Homogeneous catalysis plays an important role both in the laboratory and in the industry. Successful applications in industry involve new polymerisation processes with complexes of zirconium and related metals, new carbonylation processes…employing palladium and rhodium, ring opening polymerisations, and new enantioselective isomerisation catalysts as in the preparation of menthol. Also in the synthesis of organic compounds in the laboratory highly selective homogeneous catalysts represent an irreplaceable part of the toolbox of the synthetic chemist. Examples of such reactions are cross-coupling (Ni, Pd), nucleophilic substitution of allylpalladium complexes, Heck reactions (Pd), asymmetric epoxidation, Wacker type reactions (Pd), asymmetric hydrogenations (Rh, Ru), reactions of chromium complexes, enantioselective reactions with Lewis acids, reactions with the McMurry reagent, etc. There is hardly any multistep organic synthesis that does not involve one of these metal catalysed reactions. Most of these catalysts have been developed by empiricism. The metal catalysed processes consist of a series of elementary steps which often have been studied in isolation in organometallic chemistry. The knowl edge of such elementary steps - effect ofligands, anions, coordination number, valence states - has greatly contributed to the development of improved cata lysts for the reactions mentioned above. In addition to the empirical approach theoretical methods have given support and guidance to the development of improved processes. Often the key steps of a cycle escape from a direct ob servation and then theoretical contributions are even more wanted. 230 pp. Englisch.
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Gebunden. Condición: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Preface P.W.N.M. van Leeuwen. 1. An Introduction to Quantum Chemical Organometallic Chemistry P.H.M. Budzelaar, J.H. van Lenthe. 2. Oxidative Addition Reactions M.R.A. Blomberg, P.E.M. Siegbahn. 3. Alkene Mi…gratory Insertions and C-C Bond Formati.
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Buch. Condición: Neu. Theoretical Aspects of Homogeneous Catalysis | Applications of Ab Initio Molecular Orbital Theory | Piet W. N. M. van Leeuwen (u. a.) | Buch | v | Englisch | 1995 | Springer Netherland | EAN 9780792331070 | Verantwortliche Person für die EU: Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg, juergen…[dot]hartmann[at]springer[dot]com | Anbieter: preigu Print on Demand.
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Condición: New. Print on Demand pp. 232 52:B&W 6.14 x 9.21in or 234 x 156mm (Royal 8vo) Case Laminate on White w/Gloss Lam.
Idioma: Inglés
Editorial: Springer Netherlands, Springer Netherlands Apr 1995, 1995
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Buch. Condición: Neu. This item is printed on demand - Print on Demand Titel. Neuware -Homogeneous catalysis plays an important role both in the laboratory and in the industry. Successful applications in industry involve new polymerisation processes with complexes of zirconium and related metals, new carbonylation processes empl…oying palladium and rhodium, ring opening polymerisations, and new enantioselective isomerisation catalysts as in the preparation of menthol. Also in the synthesis of organic compounds in the laboratory highly selective homogeneous catalysts represent an irreplaceable part of the toolbox of the synthetic chemist. Examples of such reactions are cross-coupling (Ni, Pd), nucleophilic substitution of allylpalladium complexes, Heck reactions (Pd), asymmetric epoxidation, Wacker type reactions (Pd), asymmetric hydrogenations (Rh, Ru), reactions of chromium complexes, enantioselective reactions with Lewis acids, reactions with the McMurry reagent, etc. There is hardly any multistep organic synthesis that does not involve one of these metal catalysed reactions. Most of these catalysts have been developed by empiricism. The metal catalysed processes consist of a series of elementary steps which often have been studied in isolation in organometallic chemistry. The knowl edge of such elementary steps - effect ofligands, anions, coordination number, valence states - has greatly contributed to the development of improved cata lysts for the reactions mentioned above. In addition to the empirical approach theoretical methods have given support and guidance to the development of improved processes. Often the key steps of a cycle escape from a direct ob servation and then theoretical contributions are even more wanted.Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 230 pp. Englisch.
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Condición: New. PRINT ON DEMAND pp. 232.
