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Idioma: Inglés
Publicado por Brill Academic Publishers, 2005
ISBN 10: 9067644242 ISBN 13: 9789067644242
Librería: Books Puddle, New York, NY, Estados Unidos de America
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Añadir al carritoHardcover. Condición: new. Hardcover. The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems. Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown. Data on polysite phenomenon (distribution of active sites by kinetic activity and stereospecificity of action) in polymerization are analyzed. The examples of polysite phenomenon manifestation and assessment, and its connection with ion, ion-coordination and radical polymerization conditions for olefins and dienes are shown. Geometrical and electron structure of active sites in ion-coordination polymerization of dienes is considered and the relation between the structure, reactivity and stereospecificity of action of different site types is shown. Shipping may be from multiple locations in the US or from the UK, depending on stock availability.
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Añadir al carritoCondición: New. Gennady Zaikov, Yuri Monakov, Natalia Sigaeva, Vadim UrazbaevThe monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and com.
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Añadir al carritoHardcover. Condición: Brand New. 397 pages. 9.50x6.25x1.00 inches. In Stock.
Idioma: Inglés
Publicado por Brill Academic Publishers, 2005
ISBN 10: 9067644242 ISBN 13: 9789067644242
Librería: Biblios, Frankfurt am main, HESSE, Alemania
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Añadir al carritoBuch. Condición: Neu. Neuware - The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems.Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown.
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Añadir al carritoHardcover. Condición: new. Hardcover. The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems. Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown. Data on polysite phenomenon (distribution of active sites by kinetic activity and stereospecificity of action) in polymerization are analyzed. The examples of polysite phenomenon manifestation and assessment, and its connection with ion, ion-coordination and radical polymerization conditions for olefins and dienes are shown. Geometrical and electron structure of active sites in ion-coordination polymerization of dienes is considered and the relation between the structure, reactivity and stereospecificity of action of different site types is shown. Shipping may be from our Sydney, NSW warehouse or from our UK or US warehouse, depending on stock availability.
Publicado por Tashkent, 1980
Librería: BiblioEra, Everett, MA, Estados Unidos de America
EUR 177,70
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Añadir al carritoHardcover. Condición: Good. In Russian. Urazbaev, Rustam Yusupovich. Public catering and its role in improving the welfare of workers. Tashkent: o Knowledge of the Uzbek SSR, All images are for identification of editions only. Several books of the same edition may be available. Please feel free to request photos of available books.SKU1024471.
Publicado por Almaty, 1973
Librería: BiblioEra, Everett, MA, Estados Unidos de America
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Añadir al carritoHardcover. Condición: Good. Short description: In Russian. Urazbayev, Bazarbey Mambetovich. Asymptotic formulas in algebra. Alma-Ata: 1972 vol. Contact us for details or to request photos of available books. Delivery of this book could take longer than normal due to additional handling time before shipping, and no rush delivery options are available. Please let us know if you have a specific date by which you need to receive your order.SKU7077539.
Idioma: Inglés
Publicado por Brill Academic Publishers, 2005
ISBN 10: 9067644242 ISBN 13: 9789067644242
Librería: Majestic Books, Hounslow, Reino Unido
EUR 174,76
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Añadir al carritoCondición: New. pp. ix + 397 Illus. This item is printed on demand.