This volume is a very useful addition to the literature of homogeneous catalysis by transition metals/complexes and is especially useful for those interested in advanced research and development work in this area. It is bound to be appreciated by graduate students and teachers in the fields of synthetic and mechanistic organic chemistry.' Indian Journal of Chemistry (December 1985)
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Taschenbuch. Condición: Neu. Druck auf Anfrage Neuware - Printed after ordering - of Volume 2.- Hydroformylation of Olefins with Carbonyl Derivates of the Noble Metals as Catalysts.- 1. Introduction.- 2. Comparison of the Activity of Group VIII Metals.- 3. Hydroformylation with Rhodium Complexes as Catalysts.- 4. Hydroformylation with Iridium Complexes as Catalysts.- 5. Hydroformylation with Ruthenium and Osmium Complexes as Catalysts.- 6. Hydroformylation with Palladium and Platinum Catalysts.- 7. Hydrog¿tion of Aldehydes with Carbonyl Derivatives of the Noble Metals as Catalysts.- 8. Recent Results.- 9. Conclusions.- 10. References.- Addition of hydrogen cyanide to mono-olefins catalyzed by transition metal complexes.- 1. Introduction and scope.- 2. Interaction of hydrogen cyanide with metal complexes.- 3. Hydrocyanation of non-activated olefins.- 4. The proposed mechanisms of hydrocyanation.- 5. Hydrocyanation of activated olefins.- 6. Recent results.- 7. Conclusion.- 8. References.- Nickel Catalyzed Syntheses of Methyl-Substituted Cyclic Olefins, an Example of Stepwise Carbon-Carbon Bond Formation Promoted by a Transition Metal Complex.- 1. Introduction.- 2. Cope Rearrangement of 1,5-dienes.- 3. Preparation of monomethyl derivatives by methylene insertion reaction (MIR).- 4. Preparation of dimethyl derivatives by MIR.- 5. Identification of isomers using the combination gas chromatography/mass spectrometry.- 6. Catalytic syntheses of mono and dimethyl substituted ring olefins.- 7. Mechanism of carbon-carbon bond formation promoted by low valent nickel catalysts.- 8. Some general aspects of carbon-carbon and carbon-hydrogen bond formation promoted by transition metals.- 9. References.- Dimerization of Acrylic Compounds.- 1. Introduction.- 2. Thermal and photo dimerization.- 3. Dimerization by alkali metal amalgams and direct electrolysis.- 4. Phosphine-catalyzed dimerization.- 5. Dimerization by transition metal complexes.- 6. Conclusion.- 7. References. Nº de ref. del artículo: 9789401022873
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Condición: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. of Volume 2.- Hydroformylation of Olefins with Carbonyl Derivates of the Noble Metals as Catalysts.- 1. Introduction.- 2. Comparison of the Activity of Group VIII Metals.- 3. Hydroformylation with Rhodium Complexes as Catalysts.- 4. Hydroformylation with Ir. Nº de ref. del artículo: 5830191
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Taschenbuch. Condición: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -of Volume 2.- Hydroformylation of Olefins with Carbonyl Derivates of the Noble Metals as Catalysts.- 1. Introduction.- 2. Comparison of the Activity of Group VIII Metals.- 3. Hydroformylation with Rhodium Complexes as Catalysts.- 4. Hydroformylation with Iridium Complexes as Catalysts.- 5. Hydroformylation with Ruthenium and Osmium Complexes as Catalysts.- 6. Hydroformylation with Palladium and Platinum Catalysts.- 7. Hydrog¿tion of Aldehydes with Carbonyl Derivatives of the Noble Metals as Catalysts.- 8. Recent Results.- 9. Conclusions.- 10. References.- Addition of hydrogen cyanide to mono-olefins catalyzed by transition metal complexes.- 1. Introduction and scope.- 2. Interaction of hydrogen cyanide with metal complexes.- 3. Hydrocyanation of non-activated olefins.- 4. The proposed mechanisms of hydrocyanation.- 5. Hydrocyanation of activated olefins.- 6. Recent results.- 7. Conclusion.- 8. References.- Nickel Catalyzed Syntheses of Methyl-Substituted Cyclic Olefins, an Example of Stepwise Carbon-Carbon Bond Formation Promoted by a Transition Metal Complex.- 1. Introduction.- 2. Cope Rearrangement of 1,5-dienes.- 3. Preparation of monomethyl derivatives by methylene insertion reaction (MIR).- 4. Preparation of dimethyl derivatives by MIR.- 5. Identification of isomers using the combination gas chromatography/mass spectrometry.- 6. Catalytic syntheses of mono and dimethyl substituted ring olefins.- 7. Mechanism of carbon-carbon bond formation promoted by low valent nickel catalysts.- 8. Some general aspects of carbon-carbon and carbon-hydrogen bond formation promoted by transition metals.- 9. References.- Dimerization of Acrylic Compounds.- 1. Introduction.- 2. Thermal and photo dimerization.- 3. Dimerization by alkali metal amalgams and direct electrolysis.- 4. Phosphine-catalyzed dimerization.- 5. Dimerization by transition metal complexes.- 6. Conclusion.- 7. References. 204 pp. Englisch. Nº de ref. del artículo: 9789401022873
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