T�tulo: Structures and Conformations of Non-rigid Molecules: Proceedings of the NATO Advanced Research Workshop, Reisenburg, Germany, September 6-10, 1992: v. 410 (NATO ASI)
Editor: Springer
Fecha de publicaci�n: 1993
Idioma: Ingl�s
ISBN 10: 0792324153
ISBN 13: 9780792324157
Encuadernaci�n: Encuadernaci�n de tapa dura
Estado: New

Acerca de

Sinopsis

Theory.- 1. The Symmetry Groups and Rotation-Vibration Energy Levels of Some Very Nonrigid Molecules.- 2. Vibration-Inversion-Torsion-Rotation Energy Levels and Vibrational Resonances in the Methylamine Molecules.- 3. The Excited State Dynamics of Conjugated Molecules: Theoretical Studies of Slow Vibrations.- Vibrational Spectroscopy.- 4. Vibrational Potential Energy Surfaces of Non-Rigid Molecules in Ground and Excited Electronic States.- 5. Structural Information on Large Amplitude Motions.- 6. Conformational Stability of Five-Membered Ring Molecules.- 7. The Structure and Dynamics of Van Der Waals Molecules.- 8. Applications of Asymmetric Top Contour Simulation to Conformational Equilibria.- Microwave Spectroscopy.- 9. Large Amplitude Motions in Two Ring Molecules.- 10. Rotational Studies of Four-and Five-Membered Ring Molecules.- 11. Large Amplitude Motions in Molecular Complexes.- 12. Accurate Structures of Non-Rigid Molecules by Microwave Spectroscopy.- 13. Tunneling Motions in Sulfur Dioxide Complexes.- 14. Recent Gas-Phase Studies of Intermolecular Hydrogen Bonding.- 15. Millimeter- and Submillimeter-Wave Spectroscopy of Non-Rigid Transient Molecules: Analysis of Silane and Acetylene Plasmas.- Ab Initio Calculations.- 16. The Cis Monobridged Equilibrium Geometries of Si2H2, Ge2H2, Al2H2, and Ga2H2: A Fundamentally New Type of Molecular Structure.- 17. Ab Initio Anharmonic Vibrational Analyses of Non-Rigid Molecules.- 18. The Use of Natural Coordinates in Molecular Geometry Optimizations.- 19. Ab Initio Molecular Orbital Calculations of the Infrared Spectra of Interacting Water Molecules. Complexes of Water With Carbon Dioxide and Nitrous Oxide..- 20. Large Amplitude Motion In Oxalyl Chloride.- Electron Diffraction.- 21. Gas-Phase electron Diffraction Applied to Molecules Undergoing Large-Amplitude Motion.- 22. Conformational Analysis By Gas Electron Diffraction.- 23. Linear, Bent, and Quasilinear Molecules.- 24. Structures and Conformational Analysis of Monosubstituted Cyclopropanes of the Type: c-Pr-XY and c-Pr-CH -XY (X = Si,Ge; Y = H,F,Cl).- 25. Small Forces and Large Molecular Distortions.- 26. Gas-Phase Structures and Conformational Properties of Malonic Acid Derivatives, {CY2(COX)2}, as Studied By Electron Diffraction and ab Initio Calculations.- Electronic Excited States, Fluorescence Spectra, and Dynamics.- 27. Molecular Conformations in Electronic Excited States.- 28. A Comparison of the Methyl Torsion and Aldehyde Wagging Dynamics in the Ground and First Excited States of Acetaldehyde and Thioacetaldehyde.- 29. Isolation and Assignment of Organic Molecular Conformers via Laser Induced Fluorescence Spectroscopy of Jet-Cooled Molecular Beams.- 30. The Structure and Dynamics of Van Der Waals Clusters as Studied by Formation of Negative Cluster Ions.

Rese�a del editor

From the beginnings of modern chemistry, molecular structure has been a lively area of research and speculation. For more than half a century spectroscopy and other methods have been available to characterize the structures and shapes of molecules, particularly those that are rigid. However, most molecules are at least to some degree non-rigid and this non-rigidity plays an important role in such diverse areas as biological activity, energy transfer, and chemical reactivity. In addition, the large-amplitude vibrations present in non-rigid molecules give rise to unusual low-energy vibrational level patterns which have a dramatic effect on the thermodynamic properties of these systems. Only in recent years has a coherent picture of the energetics and dynamics of the conformational changes inherent in non-rigid (and semi-rigid) molecules begun to emerge. Advances have been made in a number of different experimental areas: vibrational (infrared and Raman) spectroscopy, rotational (microwave) spectroscopy, electron diffraction, and, most recently, laser techniques probing both the ground and excited electronic states. Theoretically, the proliferation of powerful computers coupled with scientific insight has allowed both empirical and ab initio methods to increase our understanding of the forces responsible for the structures and energies of non-rigid systems. The development of theory (group theoretical methods and potential energy surfaces) to understand the unique characteristics of the spectra of these floppy molecules has also been necessary to reach our present level of understanding. The thirty chapters in this volume contributed by the key speakers at the Workshop are divided over the various areas. Both vibrational and rotational spectroscopy have been effective at determining the potential energy surfaces for non-rigid molecules, often in a complementary manner. Recent laser fluorescence work has extended these types of studies to electronic excited states. Electronic diffraction methods provide radial distribution functions from which both molecular structures and compositions of conformational mixtures can be found. Ab initio calculations have progressed substantially over the past few years, and, when carried out at a sufficiently high level, can accurately reproduce (or predict ahead of time) experimental findings. Much of the controversy of the ARW related to the question of when an ab initio is reliable. Since the computer programs are readily available, many poor calculations have been carried out. However, excellent results can be obtained from computations when properly done. A similar situation exists for experimental analyses. The complexities of non-rigid molecules are many, but major strides have been taken to understand their structures and conformational processes.

"Sobre este t�tulo" puede pertenecer a otra edici�n de este libro.

Descripci�n de la librer�a

I mainly carry imported books from South East Asia / South Asia for readers of all Age Groups.

Ver la p�gina web de la librer�a

Informaci�n empresarial del vendedor

PLETOS INC
6931 51st Avenue, WOODSIDE, Woodside, NY, 11377, U.S.A.

Condiciones de venta y env�o

Condiciones de venta

We accept return for those books which are received damamged. Though we take appropriate care in packaing to avoid such situation.

Derecho al desistimiento

Si es un consumidor, puede rescindir el contrato de acuerdo con lo siguiente. Por consumidor se entiende cualquier persona f�sica que act�e con fines ajenos a su actividad comercial, empresarial, oficio o profesi�n.

Informaci�n sobre el derecho de desistimiento

Derecho legal de desistimiento

Tiene derecho a rescindir este contrato en un plazo de 14 d�as sin dar ning�n motivo.

El periodo de desistimiento vencer� a los 14 d�as desde que usted, o un tercero que no sea el transportista e indicado por usted, adquiera la posesi�n f�sica del �ltimo bien o del �ltimo lote o pieza.

Para ejercer el derecho de desistimiento, complete de forma electr�nica y env�e una declaraci�n clara en nuestro sitio web, desde "Mis compras" en "Mi cuenta". Le enviaremos sin demora un acuse de recibo de dicho desistimiento a trav�s de un soporte duradero (por ejemplo, por correo electr�nico).

Para cumplir con el plazo de desistimiento, basta con que env�e su comunicaci�n relativa al ejercicio del derecho de desistimiento antes de que venza el periodo de desistimiento.

Efectos del desistimiento

Si rescinde este contrato, le reembolsaremos todos los pagos que hayamos recibido de usted, incluidos los gastos de env�o (excepto los gastos adicionales que surjan si elige un tipo de env�o que no sea el tipo de env�o est�ndar m�s econ�mico que ofrecemos).

Podemos hacer una deducci�n del reembolso por la p�rdida de valor de cualquier bien suministrado, si la p�rdida es el resultado de una manipulaci�n innecesaria por su parte.

Efectuaremos el reembolso sin demoras indebidas y, a m�s tardar, 14 d�as despu�s de que se nos informe de su decisi�n de rescindir este contrato.

Efectuaremos el reembolso utilizando el mismo medio de pago que utiliz� para la transacci�n inicial, a menos que haya acordado expresamente lo contrario; en cualquier caso, no incurrir� en ning�n cargo como resultado de dicho reembolso.

Podremos retener el reembolso hasta que hayamos recibido los bienes o hasta que nos haya presentado una prueba de que los ha devuelto, lo que ocurra primero.

Deber� devolver los bienes o entregarlos a Books Puddle, New York, New York, U.S.A., sin demoras indebidas y, en cualquier caso, en un plazo m�ximo de 14 d�as a partir del d�a en que nos comunique su desistimiento del presente contrato. El plazo se cumple si devuelve la mercanc�a antes de que venza el periodo de 14 d�as. Tendr� que asumir los gastos directos de devoluci�n de los bienes. Usted solo es responsable de la disminuci�n del valor de los bienes como resultado de una manipulaci�n distinta a la necesaria para establecer la naturaleza, las caracter�sticas y el funcionamiento de los bienes.

Excepciones al derecho de desistimiento

El derecho de desistimiento no se aplica a lo siguiente:

La entrega de peri�dicos, diarios o revistas, con la excepci�n de los contratos de suscripci�n; y
El suministro de contenido digital que no se proporcione en un soporte tangible (por ejemplo, en un CD o DVD) si, al hacer el pedido, acept� que pod�amos empezar a entregarlo y que no podr�a desistir una vez iniciada la entrega.

Condiciones de env�o

Tarifas de env�o en Estados Unidos de America

Tarifas de env�o en Estados Unidos de America
Cantidad del pedido	De 12 a 19 d�as h�biles	De 12 a 14 d�as h�biles
Primer art�culo	EUR 3.51	EUR 6.15

Los plazos de entrega los establecen los vendedores y var�an seg�n el transportista y la ubicaci�n. Los pedidos que pasan por la aduana pueden sufrir retrasos y los compradores son responsables de los aranceles o tarifas asociadas. Los vendedores pueden ponerse en contacto con usted en relaci�n con cargos adicionales para cubrir cualquier aumento en los costes de env�o de los art�culos.