Spectroscopic Properties of Inorganic and Organometallic Compounds
Idioma: inglés
Editorial: Royal Society of Chemistry, 1977
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- Título
- Spectroscopic Properties of Inorganic and Organometallic Compounds
- Autor
- Ebsworth, E A V
- Editorial
- Royal Society of Chemistry
- Año de publicación
- 1977
- Estado
- New
- Encuadernación
- HRD
- Idioma
- inglés
- ISBN 10
- 0851860931
- ISBN 13
- 9780851860930
- Peso del artículo
- 823 gramos
Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
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Spectroscopic Properties of Inorganic and Organometallic Compounds Volume 10
A Review of the Literature Published during 1976
By E. A. V. EbsworthThe Royal Society of Chemistry
All rights reserved.
Contents
Chapter 1 Nuclear Magnetic Resonance Spectroscopy By B. E. Mann, 1,
Chapter 2 Nuclear Quadrupole Resonance Spectroscopy By R. J. Lynch, 149,
Chapter 3 Microwave Spectroscopy By A. P. Cox, 167,
Chapter 4 Vibrational Spectra of Small Symmetric Species and of Single Crystals By D. M. Adams, P. N. Gates, and P. Gans, 183,
Chapter 5 Characteristic Vibrational Frequencies of Compounds containing Main-group Elements By P. Gans, 217,
Chapter 6 Vibrational Spectra of Transition-element Compounds By M. Goldsfein, 255,
Chapter 7 Vibrational Spectra of Some Co-ordinated Ligands By G. Davidson, 296,
Chapter 8 Mössbauer Spectroscopy By J. D. Donaldson and M. J. Tricker, 360,
Author Index, 456,
CHAPTER 1
Nuclear Magnetic Resonance Spectroscopy
BY B. E. MANN
1 Introduction
The growth in papers containing n.m.r. data on inorganic and organometallic compounds has continued with the result that only papers containing information on nuclei other than H, or papers wherein H n.m.r. spectroscopy makes a significant contribution, are included. A more selective approach has also been applied within the area of solid-state n.m.r. spectroscopy, and papers which are considered to be principally of interest to physicists have been omitted. As usual, no attempt is made to cover n.m.r. spectroscopy in depth, and any reader who requires such an approach is referred to the excellent Specialist Periodical Report on 'Nuclear Magnetic Resonance'.
Volume 8 of 'Advances in Magnetic Resonance' has appeared and contains chapters on 'The Theory of Chemically Induced Dynamic Spin Polarization', by H. H. Freed and J. B. Pedersen, and 'N.M.R. in Flowing Systems', by D. W. Jones and T. F. Child. In addition, the first supplement to this series on 'High Resolution N.M.R. in Solids, Selective Averaging', by U. Haeberlen has appeared. Volume 6B of 'Annual Reports on N.M.R. Spectroscopy' contains chapters on 'N.M.R. and Conformations of Amino Acids, Peptides, and Proteins', by W. A. Thomas, and 'Fluorine-19 N.M.R. Spectroscopy', by L. Cavalli. The series 'N.M.R., Basic Principles and Progress' has proved to be prolific with books on 'Van der Waals Forces and Shielding Effects', by F. H. A. Rummens, 'High Resolution N.M.R. Spectroscopy in Solids', by M. Mehring,'Chlorine, Bromine, and Iodine N.M.R. Physico-chemical and Biological Applications', by B. Lindman and S. Forsén, and 'Introductory Essays', edited by M. M. Pintar, containing 11 essays on various n.m.r. topics, none of which is of direct relevance to this chapter. 'Progress in Nuclear Magnetic Resonance Spectroscopy' has produced a review on 'Spin-Spin Coupling and the Con-formational States of Peptide Systems', by V. F. Bystrov. The second volume of 'Topics in Carbon-13 N.M.R. Spectroscopy' has now appeared and contains a number of chapters on various aspects of 13C n.m.r. spectroscopy, and in particular 'Carbon-13 N.M.R. Studies of Organometallic and Transition Metal Complex Compounds', by O. A. Gansow and W. D. Vernon.
A number of books devoted to n.m.r. spectroscopy have been published, including 'Proton Nuclear Magnetic Resonance', by P. Joseph-Nathan; 'The Dynamics of Spectroscopic Transition: Illustrated by Magnetic Resonance and Laser Effects', by J. D. Macomber; 'Spectroscopic Methods for Determining the Structure of Organic Compounds. Section "Nuclear Magnetic Resonance Spectroscopy", by J. Prochorow; 'Magnetic Resonance', edited by C. A. McDowell, which contains chapters on 'High Resolution N.M.R. Studies on Solids', by E. R. Andrew, 'The Studies of Ionic Processes at Membranes by N.M.R. Methods', by L. W. Reeves, and 'Tunnelling Processes as Studied by Magnetic Resonance Techniques', by R. Srinivasan; 'Fourier Transform N.M.R. Spectroscopy', by D. Shaw; 'Use of Nuclear Magnetic Relaxation in the Analysis of Inorganic Compounds', by A. A. Popel; 'Interpretation of Carbon-13 Nuclear Magnetic Resonance Spectra', by F. Wehrli and T. Wirthlin; 'Spectroscopic Methods in Pharmacy, Vol. 2: Nuclear Magnetic Resonance Spectroscopy and Mass Spectrometry', by G. Ruecker; 'Magnetic Resonance of Biomolecules', by P. F. Knowles, D. Marsh, and H. W. E. Rattle; 'Nuclear Magnetic Resonance in Biological Research: Peptides and Proteins', by K. Wuethrich ; 'Nuclear Magnetic Resonance in Biochemistry', by T. L. James; a collection of lectures in 'Magnetic Resonance in Chemistry and Biology'; and 'Corso Teorico-Pratico di Resonanza Magnetica Nucleare', edited by A. Frigerio.
Several other books have appeared which contain sections or chapters devoted to n.m.r. spectroscopy. These books have articles on 'Physical Methods and Techniques; 11. Nuclear Magnetic Resonance', by R. B. Jones and L. Phillips; 'Nuclear Magnetic Resonance Spectroscopy', by I. O. Sutherland; 'N.M.R. of Nuclei other than Proton and Fluorine-19', by G. A. Webb; 'Correlations in Nuclear Magnetic Shielding, Part l', by J. Mason; 'Si Nuclear Magnetic Resonance', by J. Schraml and J. M. Bellama; 'The Nuclear Overhauser Effect', by J. K. Saunders and J. W. Easton; 'Molecular Structure by N.M.R. in Liquid Crystals', by L. Lunazzi ; and 'N.m.r. Parameters of the Proton Directly Bonded to Phosphorus'.
Once again numerous reviews have appeared. Some of the reviews are of n.m.r. spectroscopy in general. Other reviews cover 'High-resolution N.M.R. Method', 'N.M.R. as an Analytical Technique', 'Nuclear Magnetic Resonance as the Stereochemists' Tool', 'Determination of Molecular Conformation in Solution', 'Conformational Analysis using High-resolution N.M.R. Spectroscopy', 'Nuclear Magnetic Resonance Techniques for the Determination of the Structure of Molecules', 'Recent N.M.R. Applications in Organic Chemistry', 'Nuclear Magnetic Resonance at High Pressures', 'Basics of N.M.R. Spectroscopy', 'Practical Interpretations of N.M.R. Spectra', 'Pulsed N.M.R. Spectrometry', 'Proton N.M.R. Spectrometry', 'Analysis of N.M.R. Spectra', 'Allylic Interproton Spin-Spin Coupling', 'Influence of Solvents on Spectroscopy', 'Solute-Solute and Solute-Solvent Interactions: N.M.R. Studies', 'Forbidden Transition in Magnetic Resonance', 'Spin Relaxation in Fluids', 'Magnetic Relaxation', 'Reorientation and Dipole Relaxation', 'N.M.R. and the Periodic Table', 'The Application of Carbon-13 N.M.R. to Oil Chemistry. Part 2. Review of Recent Topics',7 'Carbon-13 N.M.R. Spectroscopy'," 'Carbon-13 Fourier Transform N.M.R. An Important New Analysis Tool', 'Applications of C and lH N.M.R. and I.R. Spectro-scopies in Structural and Quantitative Analysis', 'c N.M.R. Use in Organic Chemistry, Biochemistry, and Technology',6 'The Application of Carbon-13 N.M.R. Spectroscopic Techniques to Biological Problems', 'C N.M.R. Spectroscopy in Organic Chemistry', 'The Use of Alkali Metal N.M.R. in the Study of Solvation and Complexation of Alkali Metal Ions', 'Dynamic N.M.R. of Carbon', 'Unusually High Barriers to Rotation Involving the Tetrahedral Carbon Atom', 'Nuclear Magnetic Resonance Studies of Coordination Compounds', 'Nuclear Magnetic Resonance Spectroscopy of Porphyrins and Metalloporphyrins', 'Investigations of Hydrides of the Group IVa and Va Metals by Nuclear Magnetic Resonance', 'N.M.R. Spectroscopy of Iron-Sulphur Proteins', 'Apicophilicity and Ring Strain in Five-coordinate Phosphoranes', 'Organic and Inorganic Reaction Mechanisms Using Oxygen-17', 'Chemically Induced Dynamic Nuclear Polarization and Chemically Induced Dynamic Electron Polarization', 'N.M.R. in Drug Metabolism', 'N.M.R. in the Field of Biochemistry', and 'N.M.R. Spectroscopy in Biological Sciences', 'N.M.R. Spectroscopy in Biological Research', 'Use of N.M.R. for the Study of the Structure and Function of Enzymes', and 'The Calculation of NM.R. Lineshapes of Glasses'.
I.U.P.A.C. have published revised recommendations for the 'Presentation of N.M.R. data for publication in chemical journals - B. Conventions relating to spectra from nuclei other than protons'. All workers in this area are strongly urged to read these recommendations. Difficulties are commonly encountered as a result of the use of the wrong chemical shift sign convention and not defining the sign convention. These difficulties are particularly common for P n.m.r. spectroscopy where a 31P chemical shift of say δ10 can mean a shift to either high or low frequency (high frequency would be assumed) of an unknown reference, normally assumed to be 85% H3PO4. Similar difficulties can be encountered with other nuclei, especially 1H, 13C, and 19F. Throughout this chapter, authors permitting, the sign convention that high frequency is positive is adopted.
In addition to these books and reviews, papers have appeared which are too broadly based to fit into any of the later sections of this chapter and are included here. The valence bond treatment of the Fermi contact term for nucleus-nucleus coupling constants gave simplified expressions in which a constant term for each nucleus was introduced. The order of the bond separating the coupled nuclei was estimated. This approach was applied to long-range hydrogen-metal and carbon-metal coupling constants in organometallic compounds. 17O, 35Cl, 51V, 53Cr, 55Mn, and 95MO n.m.r. spectra have been determined for aqueous solutions of [FORMULA NOT REPRODUCIBLE IN ASCII] and [MoO4]2-, partly enriched in 70. The following coupling constants were determined: [FORMULA NOT REPRODUCIBLE IN ASCII]. A linear dependence of the reduced coupling constant on the atomic number of the central nucleus in the isoelectric series [FORMULA NOT REPRODUCIBLE IN ASCII] and [MnO4]- was found. The mutual influence of ligands in main-group element co-ordination compounds ALn has been analysed on the basis of the orbitally deficient scheme of the structure of these compounds. It was shown that a decrease of the A-19F bond strength can be accompanied by an increase of [FORMULA NOT REPRODUCIBLE IN ASCII]. A statistical method has been suggested to analyse the temperature-dependent n.m.r. relaxation in order to determine structural and kinetic parameters of metal ion complexes in solution. F Solvate isotope shifts of several inorganic fluoro-complexes of Group II, III, IV, V, and VI metals have been carried out. Isotope shifts were compared with the effective charge and their distribution in fluoride-containing anions. The possibility of using F solvate isotope shifts to establish unfamiliar complex anions and their hydration was discussed. The 19F n.m.r. spectra of m- and [FORMULA NOT REPRODUCIBLE IN ASCII] derivatives show that 19F shielding is a useful probe of [FORMULA NOT REPRODUCIBLE IN ASCII] π-bonding effects in ArN2] complexes as long as the compound is confined to complexes of the same structural type (singly-bent ArN2]+ in the present case). For the complexes studied a total range of 10 p.p.m. was recorded for (δp - δm] the shielding parameters becoming progressively more positive as conjugative transfer of electron density along the [FORMULA NOT REPRODUCIBLE IN ASCII] chain decreased. Arranging complexes in order of increasing δp - δmgives a sequence which is in excellent agreement with the ranking of [FORMULA NOT REPRODUCIBLE IN ASCII] π-bonding anticipated on the basis of relative donor and acceptor powers of co-ligands and the formal oxidation state of the metal atom. The 19F n.m.r. technique was extended to pprovide the first unambiguous evidence that the [ArN2] + ligand is a poorer π-acceptor than [NO]+. The 13C n.m.r. spectra of several metal enolates have been examined in various aprotic solvents and compared with those of enol acetates and Me3SiO ethers. The chemical shift difference between enolates and enolacetates appears to be related both to the π-electron density and reactivity at the enolate π-carbon atom. Diamagnetic metal complexes of propane 1,3-diamine-NNN'N'-tetra-acetate ([pyta]4-) have been studied by 3C n.m.r. spectroscopy. The results confirm previous studies in showing that complexes in which the ligand is quinquedentate are not formed (except possibly with HgII) but also show that this is due not to decreased ring strain in the six-co-ordinate complex but rather to steric compression of the glycinate chelate arms arising from the bunched backbone methylene groups. At low pH the complex formed between [pyta4- and AlIII is more inert than the analogous [edta]4- complex despite the lower equilibrium formation constant, and this is in line with the reduced tendency of [pyta]4- to form complexes in which the ligand is quinquedentate.
2 Stereochemistry
This section is subdivided into ten parts which contain n.m.r. information about hydrogen, lithium, sodium, beryllium, magnesium, and transition-metal complexes, presented by Groups, according to the Periodic Table. Within each Group classification is by ligand type. As far as possible, cross- references are given at the beginning of each sub-group to compounds discussed elsewhere in this chapter. In this cross- referencing, it has not proved possible within the space available to include the many compounds that occur within the sections on dynamic systems, paramagnetic systems, and solid-state n.m.r. spectroscopy. Thus many more compounds of relevance to this section appear elsewhere.
Complexes of Group I and II Elements. — Information on [FORMULA NOT REPRODUCIBLE IN ASCII] is given later (ref. 1136). A review entitled 'Nuclear Magnetic Resonance and its Use in the Study of Chlorophylls' has appeared.
The contact contribution to [FORMULA NOT REPRODUCIBLE IN ASCII] in HD has been calculated to be 39 Hz, cf. 42.94 Hz (experimental). 13C N.m.r. spectroscopy and [FORMULA NOT REPRODUCIBLE IN ASCII] have been used to investigate α-lithio-sulphoxides and sulphones. CNDO/2 Calculations have been performed on (Me2O)2Li (pentadienyl), and the calculated charge densities when compared with 13C n.m.r. data gave qualitative agreement. The optical pumping method of alkali molecules by atom-molecule exchange collisions has been applied to obtain the magnetic shielding difference [FORMULA NOT REPRODUCIBLE IN ASCII] between sodium atoms and Na2 molecules, and the scalar nuclear spin-spin coupling constant [FORMULA NOT REPRODUCIBLE IN ASCII]. Magnetic quantum transitions for spin 3/2 nuclei in n.m.r. spectra in lyotropic liquid crystals have been observed for 23Na+. The magnetic shielding of 133Cs in Cs+, Cs2, and free atoms has been determined. [FORMULA NOT REPRODUCIBLE IN ASCII] and [FORMULA NOT REPRODUCIBLE IN ASCII] have been reported for [FORMULA NOT REPRODUCIBLE IN ASCII]and related molecules. The results indicate that neither the 13C chemical shift nor [FORMULA NOT REPRODUCIBLE IN ASCII] may be used as a criterion for assigning a π or σ-bonded structure. For [FORMULA NOT REPRODUCIBLE IN ASCII]. 1H Spin-lattice relaxation measurements have been used to assign signals of metalloporphyrin and chlorophyll n.m.r. spectra. 1H and C n.m.r. spectroscopies have been used to demonstrate that aggregation of MgII porphyrins involves the magnesium in one molecule and the propionate carbonyl in another, whereas in zinc porphyrins, aggregation is independent of the side-chains. A similar 13C n.m.r. study of the relative donor properties of the three carbonyl groups of chlorophyll a has provided evidence that the donor-acceptor interactions that bind the chlorophyll dimer together involve a substantial participation by the ring V keto-carbonyl and minimal participation by the Z ester carbonyl groups.
Complexes of Sc, Y, U, Ti, and Zr. — Information concerning complexes of these elements can be found at the following sources: [FORMULA NOT REPRODUCIBLE IN ASCII](M = Ti, Zr, or Hf), [(η5-cycloheptadienyl)(η7 -cycloheptatrienyl)Ti], and [Ti(tetra-phenylporphyrin)O].
The 1H and 13C n.m.r. spectra of (1; M = Sc or Y) have been measured. For [FORMULA NOT REPRODUCIBLE IN ASCII], and [FORMULA NOT REPRODUCIBLE IN ASCII]. For the [FORMULA NOT REPRODUCIBLE IN ASCII] group, the first [FORMULA NOT REPRODUCIBLE IN ASCII] was observed. The 100 MHz n.m.r. spectra of Sc, T1, and Pb octaethylporphyrin and of a μ-oxo dimer of Sc octaethylporphyrin show the methylene protons of the ethyl side-chains to be anisochronous. The 100 and 300 MHz n.m.r. spectra of TI aetioporphyrin show that the methylene protons of the four ethyl side-groups of this porphyrin are also anisochronous. It was suggested that these phenomena result from the inherent asymmetry of metalloporphyrins rather than from hindered rotation of the side-chains. 19F N.m.r. spectra have been reported for [FORMULA NOT REPRODUCIBLE IN ASCII]and [FORMULA NOT REPRODUCIBLE IN ASCII].
The 1H and 13C n.m.r. spectra of [FORMULA NOT REPRODUCIBLE IN ASCII] show [FORMULA NOT REPRODUCIBLE IN ASCII]. The Lewis acidity of RTi(OCMe3)3 has been related to the 1H shifts of the methyl group and attributed to π-bonding. The 13C chemical shifts of a large series of cyclopentadienyl derivatives of titanium and iron have been measured. Substituent- and trans-effects were investigated. The 13C n.m.r. spectra of [FORMULA NOT REPRODUCIBLE IN ASCII] have yielded information on the charge on the carbon atoms. For M = Cr, the carbon atoms of the five-membered ring are more shielded than those of the seven-membered ring. For M = Ti, the reverse is true. Chemical shift considerations make it clear that for M = Cr, the carbon atoms of the five-membered rings are more negatively charged than those of the seven-membered ring. For M = Ti, the highest negative charge is on the carbon atoms of the seven-membered ring. The replacement of the 3d metal by the corresponding 4d metal causes a high-frequency shift for the signals of the carbon atoms of the five-membered ring and a low-frequency shift for the carbon atoms of the seven-membered ring. This results in an inversion of signals for M = Mo with respect to M = Cr. However, it was not clear in this conference abstract how the charge effect on chemical shifts was separated from all the other contributions. The solution N n.m.r. spectrum of [FORMULA NOT REPRODUCIBLE IN ASCII] supports the solid-state X-ray structure with two signals with [FORMULA NOT REPRODUCIBLE IN ASCII] and at δ = 160.4 a low-frequency singlet due to [FORMULA NOT REPRODUCIBLE IN ASCII].
(Continues...)
Excerpted from Spectroscopic Properties of Inorganic and Organometallic Compounds Volume 10 by E. A. V. Ebsworth. Copyright © 1977 The Chemical Society. Excerpted by permission of The Royal Society of Chemistry.
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Our people
COLLECTION:
We will collect names, addresses, contact details, education and employment history, identity and other background checks (which may include appropriate criminal and financial checks and confirmation of the right to work in the UK), marital status and information on next of kin and dependents, financial information (such as bank details and NI numbers), date of birth, gender, a copy of your passport and driving licence, performance information and compensation history, recruitment information (including references), salary, benefits, pension and annual leave information, disciplinary and grievance information, photographs, information about your use of our information and communications systems and CCTV footage or other information obtained through electronic means.
We may collect and use special categories of personal data as required in the carrying out of obligations and exercising specific rights of us or the data subject in the field of employment. This may include information relating to matters such as health, racial origin, religious belief and offences or alleged offences.
Personal data may be collected from you during the selection process (for example via your application form and CV) and during your employment (including holiday forms, expense claims, performance reviews, any disciplinary or grievance processes), or from third parties, including referees, health service providers, background check providers.
USE:
Personal data of our people will be used for HR administration and management, both in respect of the selection of people to work for us (including suitability, eligibility and/or fitness to work), and those who do work for us, to include learning and development, disciplinary and security (of people, offices and data) requirements, providing and liaising with benefits providers, business management and planning (including accounting and auditing), paying you and dealing with tax and NI deductions, assessing and deciding on salary reviews and compensation, conducting performance reviews and managing performance, dealing with legal disputes involving you or others, preventing fraud, monitoring your use of our information and communications systems, ensuring compliance with our policies, and equal opportunities monitoring.
We will only use your personal data when the law allows us to. Most commonly, we will use your personal data in the following circumstances:
In performance of a contract with you; and/or
compliance with a legal obligation; and/or
vital interests of the data subject; and/or
where it is necessary for our legitimate interests (or those of a third party) and your interests and fundamental rights do not override those interests.
We may also use your personal data in the following situations, which are likely to be less common:
where we need to protect your interests (or someone else’s interests);
where it is needed in the public interest or for official purposes.
In respect of all disclosures of personal data, we will only share the personal information which is necessary for the particular purpose for which it is provided, or where we have another legitimate interest in doing so, and we will ensure that the personal data is appropriately protected.
In respect of special categories of personal data, we may process this in the following circumstances:
in limited circumstances with your explicit written consent; and/or
where we need to carry out our legal obligations and in line with our policies; and/or
where it is needed in the public interest (such as for equal opportunities monitoring or in relation to our occupational pension scheme), and in line with our policies; and/or
where it is needed to assess your working capacity on health grounds, subject to appropriate confidentiality safeguards.
Less commonly, we may process this type of information where it is needed in relation to legal claims or where it is needed to protect your (or someone else’s) interests and you are not capable of giving your consent, or where you have already made the information public. We may also process such information about our people (or former people) in the course of our legitimate business activities with the appropriate safeguards.
The special categories of personal data may be used in the following ways:
in relation to leaves of absence, to comply with employment and other laws;
in relation to your physical or mental health, or disability status, to ensure your health and safety in the workplace and to assess your fitness to work, to monitor, manage and administer benefits and absences;
in relation to your race, national or ethnic origin, religious, philosophical or moral beliefs, or your sexual life or sexual orientation, to ensure meaningful equal opportunity monitoring and reporting.
DISCLOSURE:
Personal data may be transferred to service providers who support the operation of our business (such as payroll service providers), to other third parties reasonably necessary in the conduct of our business (including insurers, professional advisors, regulators). These third parties may be acting as processor, or controller of personal data in their own right.
In respect of all disclosures of personal data, we will only share the personal information which is necessary for the particular purpose for which it is provided, or where we have another legitimate interest in doing so, and we will ensure that the personal data is appropriately protected.
RETENTION PERIOD:
We will keep personal data only for as long as is necessary to fulfil the purposes for which we collected it, including for the purposes of satisfying any legal, accounting or reporting requirements. We will normally keep personal data of applicants who we do not employ for six months after we receive it.
We will keep personal data of employees throughout your employment and normally for a minimum of six years after your employment ends.
Changes to your personal data
It is very important that the personal information that we hold about you is accurate and current. Please tell us if your personal information changes during your relationship with us.
Data Security
We have put in place measures to prevent your personal data from being accidentally lost, used or accessed in an unauthorised way, altered or disclosed. In addition, we limit access to your personal data to those of our people and other third parties who have a business need to know. They will only process your personal data on our instructions and where they have agreed to treat the information confidentially and to keep it secure. We have put in place procedures to deal with any suspected data security breach and will notify you and the ICO of a suspected breach where we are legally required to do so.
Where we store your personal data
We principally store data, both electronically and on file, at our office.
Personal data may be transferred outside of the EEA by processors acting on our behalf. For transfers to countries not considered adequate by the EC, we will ensure that personal data is adequately protected, as required by the GDPR. This would include by use of the Standard Contractual Clauses adopted by the EC to protect personal data.
Your rights
Under certain circumstances, you have the right by law to request:
access to your personal data. This enables you to ask to receive a copy of the personal data that we hold about you and to check that we are lawfully processing it.
correction of the personal data that we hold about you.
erasure of your personal data.
object to processing of your personal data where we are relying on our legitimate interest and there is something about your particular situation which makes you want to object to processing on this ground. You also have the right to object where we are processing your personal information for direct marketing purposes.
restriction of processing of your personal data.
transfer of your personal data to another party.
Links from our website
Our website may, from time to time, contain links to and from the websites of third parties that we permit to make such links. If you follow a link to any of these websites, please note that these websites have their own privacy policies and that we do not accept any responsibility or liability for these policies. We recommend that you check these policies before you submit any personal data to these websites.
CHANGES TO THIS PRIVACY POLICY
Any changes we may make to our privacy policy in the future will be posted on our website, so please ensure that you are viewing the correct version.
Please contact us if you have any questions, comments or requests regarding this Privacy Policy.
Last amended May 2021.