Highlights in Solute-Solvent Interactions (Monatshefte Fur Chemie/Chemical Monthly, 132) - Tapa dura
Sinopsis
This book emphasizes a broad spectrum of features in solution chemistry, reaching from recent developments in the empirical characterization of solvent-solute interactions up to modern theoretical descriptions of liquid-state systems, from solid-liquid interfaces to preferential solvation in mixed solvents. Accordingly, this collection presents the most important, though strongly different approaches to the understanding of the mutual influences between solute and solvent. Descriptions of actual and practically useful applications of these concepts are included.
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Reseña del editor
Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance.
Reseña del editor
This book emphasizes a broad spectrum of features in solution chemistry, reaching from recent developments in the empirical characterization of solvent-solute interactions up to modern theoretical descriptions of liquid-state systems, from solid-liquid interfaces to preferential solvation in mixed solvents. Accordingly, this collection presents the most important, though strongly different approaches to the understanding of the mutual influences between solute and solvent. Descriptions of actual and practically useful applications of these concepts are included.
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Highlights in Solute-Solvent Interactions
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Springer Vienna Dez 2001, 2001
ISBN 10: 3211837310
ISBN 13: 9783211837313
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Buch. Condición: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the 'outer sphere' kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance. 236 pp. Englisch. Nº de ref. del artículo: 9783211837313
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Condición: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the outer sphere kind, the choice of solvent can be critical to the successful. Nº de ref. del artículo: 4489214
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Condición: Sehr gut. Zustand: Sehr gut | Sprache: Englisch | Produktart: Bücher | Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance. Nº de ref. del artículo: 951898/2
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Buch. Condición: Neu. Highlights in Solute-Solvent Interactions | Wolfgang Linert | Buch | Englisch | 2001 | Springer Vienna | EAN 9783211837313 | Verantwortliche Person für die EU: Springer Wien, Prinz-Eugen-Str. 8-10, 1040 WIEN, ÖSTERREICH, buchhandel-buch[at]springer[dot]com | Anbieter: preigu Print on Demand. Nº de ref. del artículo: 104203597
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