Volume 25: Optical Methods of Investigating Solid Bodies (The Lebedev Physics Institute Series) - Tapa blanda

 
9781468472080: Volume 25: Optical Methods of Investigating Solid Bodies (The Lebedev Physics Institute Series)
Tapa blanda
ISBN 10: 1468472089 ISBN 13: 9781468472080
Editorial: Springer, 2013

Sinopsis

The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3’ SbP3’ As 0 • SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3’ Ge02’ Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3’ Ge02’ Te02 are simi­ lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec­ tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td’ The force constants and vibration fre­ 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re­ 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated.

"Sinopsis" puede pertenecer a otra edición de este libro.

Reseña del editor

The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3' SbP3' As 0 · SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3' Ge02' Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3' Ge02' Te02 are simi­ lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec­ tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td' The force constants and vibration fre­ 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re­ 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated.

"Sobre este título" puede pertenecer a otra edición de este libro.

Editorial
Springer
Año de publicación
2013
Idioma
Inglés
ISBN 10 
1468472089
ISBN 13 
9781468472080
Encuadernación
Tapa blanda
Número de páginas
196
Editor
Skobel Tsyn D. V.
Contacto del fabricante
ProductSafety@springernature.com
ProductSafety@springernature.com

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