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Chemical Reactions in Complex Mixtures - Tapa dura

Sapre, Ajit V.

 
9780442007256: Chemical Reactions in Complex Mixtures

Sinopsis

In recent years there has been a convergence of trends in chemical reaction engineering and chemistry which have set the stage for significant advances in kinetic and thermodynamic modeling of processes. New analytical chem­ istry methods, new mathematical methods, and new computational tools facilitate a more fundamental approach and a deeper understanding of chemical reactions in complex mixtures with very large numbers of com­ pounds, such as petroleum fractions. This fortunate state of affairs has stimulated important new work both in academia and industrial research labs. The purpose of the workshop that led to this book was to bring together researchers at the forefront ofthis field to review the state of the art, stimulate communication and cooperation between industry and academia, and develop a cohesive picture of research trends and future directions. The chapters of the book have been organized into four main areas: Continuous mixtures, where the very large numbers of discrete com­ pounds present are regarded as making up a continuum, Structure-activity relationships, where the nature and rates of the reac­ tions that a particular molecule undergoes are correlated with its chemical structure, thus allowing the kinetics of very large numbers of compounds to be described by a few parameters, Kinetic analysis, where mathematical techniques are applied to analyze the behavior of kinetic networks, and Thermodynamics, emphasizing the practical and computational aspects of chemical equilibrium in complex mixtures.

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Reseña del editor

This is a new look at chemical complex systems seen in the light of the growing industrial reliance on very large numbers of compounds and dramatic advances in computation tools for analysis and prediction. The book reviews the state of the science, revisits fundamentals of stoichiometry, thermodynamics, and kinetics, and develops a coherent picture of future research needs and directions. It covers the major applications for practical modelling of complex chemical systems throughout chemical engineering and deals with topics of emerging interest, such as hazards control; chemical reaction engineering of multicomponent mixtures; comparison of lumping versus continuum approaches, and group contribution methods applied to kinetics and thermodynamics. It also features a thorough discussion of complex systems relevant to the chemical and petroleum industries. This book should be of interest to chemists and chemical engineers in the petroleum, petrochemical, and chemical industries.

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