Comprehensive Organic Functional Group Transformations, Volume 4: Synthesis: Carbon with Two Heteroatoms, Each Attached by a Single Bond - Tapa dura

Comprehensive Organic Functional Group Transformations: Volume 4, Synthesis: Carbon with Two Heteroatoms, Each Attached by a Single Bond

Hardcover. Condición: Near Fine. Estado de la sobrecubierta: Very Good. 0080423256. Red cloth hardcover with gold lettering on the spine and front board, in a very good dust jacket. 1352 pages, indexes, illustrated. Discusses the synthesis of familiar functional groups, notably acetals, dithioacetals, aminals and the various mixed species. The derivatives with tetracoordinated (saturated) carbon are described in Part I and those, eg. ketene acetals, of tricoordinated carbon in Part II. However, the treatment is comprehensive and the authors have uncovered much fascinating chemistry concerning less familiar groups, including some like geminal halohydrins, halo amines and diols that are often unstable. A surprisingly large number of compounds having two metals attached to the same carbon have been located in the literature, and the abundance of phosphorus derivatives, eg. those with geminal nitrogen functions, reflects their importance as biologically active species and intermediates in synthesis. Part III consists of a single, short chapter describing dicoordinate carbon (carbenes) and examples of carbon cations, anions and radicals. Emphasis is placed on the synthesis of isolable species rather than the transient intermediates of organic reactions. Contents, clean, tight and bright. Book. Nº de ref. del artículo: 029737

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