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Publicado por E Cuvillier, 2016
ISBN 10: 3736992513ISBN 13: 9783736992511
Librería: buchversandmimpf2000, Emtmannsberg, BAYE, Alemania
Libro
Broschiert. Condición: Gebraucht. Gebraucht - Gut Gebraucht - gut - ganz leichter Knick im einband, mit leichten Mängeln an Schnitt oder Umschlag durch Lager- oder Transportschaden, Mängelexemplar, ungelesen -The synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazolate bridges are well suited. Especially the latter ones were generated to synthesis highly preorganised bimetallic complexes with tuneable metal metal separations in the range 3.5¿4.5 Å. Appending second sphere functions for H-bonding interactions may enhance, in a biomimetic approach, the activation of bound substrates or the stabilisation of catalytic intermediates. With these ligands, synthetic and functional model complexes based on the proteins urease, phosphotriesterase and hemocyanin should be synthesised and characterised on their binding properties and their abilities to transform biorelevant substrates like urea, phosphoesters and dioxygen. For their characterisation and catalytical properties several analytical methods like UV/vis, IR, NMR and resonance Raman spectroscopy as well as mass spectrometry were used. 252 pp. Englisch.
Publicado por Cuvillier Mai 2016, 2016
ISBN 10: 3736992513ISBN 13: 9783736992511
Librería: BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, Alemania
Libro Impresión bajo demanda
Taschenbuch. Condición: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazolate bridges are well suited. Especially the latter ones were generated to synthesis highly preorganised bimetallic complexes with tuneable metal¿¿¿metal separations in the range 3.5¿4.5 Å. Appending second sphere functions for H-bonding interactions may enhance, in a biomimetic approach, the activation of bound substrates or the stabilisation of catalytic intermediates. With these ligands, synthetic and functional model complexes based on the proteins urease, phosphotriesterase and hemocyanin should be synthesised and characterised on their binding properties and their abilities to transform biorelevant substrates like urea, phosphoesters and dioxygen. For their characterisation and catalytical properties several analytical methods like UV/vis, IR, NMR and resonance Raman spectroscopy as well as mass spectrometry were used. 252 pp. Englisch.
Publicado por Cuvillier, 2016
ISBN 10: 3736992513ISBN 13: 9783736992511
Librería: AHA-BUCH GmbH, Einbeck, Alemania
Libro Impresión bajo demanda
Taschenbuch. Condición: Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - The synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazolate bridges are well suited. Especially the latter ones were generated to synthesis highly preorganised bimetallic complexes with tuneable metal¿¿¿metal separations in the range 3.5¿4.5 Å. Appending second sphere functions for H-bonding interactions may enhance, in a biomimetic approach, the activation of bound substrates or the stabilisation of catalytic intermediates. With these ligands, synthetic and functional model complexes based on the proteins urease, phosphotriesterase and hemocyanin should be synthesised and characterised on their binding properties and their abilities to transform biorelevant substrates like urea, phosphoesters and dioxygen. For their characterisation and catalytical properties several analytical methods like UV/vis, IR, NMR and resonance Raman spectroscopy as well as mass spectrometry were used.
Publicado por Jentzsch-Cuvillier, Annette, 2016
ISBN 10: 3736992513ISBN 13: 9783736992511
Librería: moluna, Greven, Alemania
Libro Impresión bajo demanda
Condición: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. KlappentextrnrnThe synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazol.