Contemporary Metal Boron Chemistry I: Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides: 130 (Structure and Bonding) - Tapa blanda

9783642097393: Contemporary Metal Boron Chemistry I: Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides: 130 (Structure and Bonding)

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ISBN 10: 3642097391 ISBN 13: 9783642097393

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With information that will remain valid for years, this series presents critical reviews of the present position and future trends in modern research into chemical structure and bonding. It features concise reports, each written by world-renowned experts.

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ISBN 10 3642097391
ISBN 13 9783642097393
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EditorMarder Todd B., Lin Zhenyang

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9783540786337: Contemporary Metal Boron Chemistry I: Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides: 130 (Structure and Bonding)

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Contemporary Metal Boron Chemistry I: Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides (Structure and Bonding) [Paperback ]

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Contemporary Metal Boron Chemistry I: Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides (Structure and Bonding, 130)

Publicado por Springer (2010)

ISBN 10: 3642097391 ISBN 13: 9783642097393

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Contemporary Metal Boron Chemistry I

Marder, Todd B.|Lin, Zhenyang

Publicado por Springer Berlin Heidelberg (2010)

ISBN 10: 3642097391 ISBN 13: 9783642097393

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Descripci�n Condici�n: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. This series presents critical reviews of the present position and future trends in modern chemical research concerned with chemical structure and bondingShort and concise reports, each written by the world s renowned expertsStill valid and . N� de ref. del art�culo: 5048736

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Contemporary Metal Boron Chemistry I

Zhenyang Lin

Publicado por Springer Berlin Heidelberg Nov 2010 (2010)

ISBN 10: 3642097391 ISBN 13: 9783642097393

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Descripci�n Taschenbuch. Condici�n: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The eld of metal boron chemistry has been an especially active one since the 1960s. Much of the early work centered on the synthesis and structural characterization of polyhedral metallaborane and metallacarborane clusters, which will not be discussed in the current Volume. However, early work on metal boryl complexes by N�th et al. also appeared during this period, - thoughthe rstsimple metalborylcomplexestobestructurallycharacterized bysingle-crystalX-raydiffractionwerenotreporteduntil1990(indeed,crystal structuresofiridiumhydridoborylcomplexeswerereportednearlysimulta- ouslybyBaker,Marder,etal. [1]andbyMerolaetal. [2]),andthisnewinterest in the area arose speci cally as a result of the report by N�th et al. [3] on the rhodium-catalyzed hydroborationof alkenes using catecholborane. Although there had been previous reports of metal-catalyzed hydroboration employing polyhedralboranesorcarboranesastheB Hsource[4], theseminal paper by N�th et al. in 1985 [3] marked the beginning of interest by the organic ch- istry community in the application of this reaction in organic synthesis [5]. Whatensuedwasaveryrapidincreaseinthenumberofmetalborylcomplexes to be synthesized and structurally characterized, along with studies of their reactivity,in conjunctionwithan equally rapid growthinthedevelopment of catalytichydroborationchemistry[5]anditsasymmetricversion[5e]. Thiswas followedbyawidevarietyofotherborylationreactionscatalyzedbytransition metals including diborations, silylborations, stannylborations, and thiabo- tions of unsaturated organic substrates [6], borylations of , -unsaturated carbonyl compounds [7], borylations of C halide bonds [8], and most - cently, borylations of C H bonds in alkenes, arenes, heteroarenes, and even alkanes[9,10]. TheC halideandC Hborylationchemistryhasbeendrivenby thedevelopment andbroadapplicationoftheSuzuki Miyaura cross-coupling reaction[11],whichisnowoneofthemainC Cbond-formingreactionsinthe arsenal of the organic chemist. Thus, the synthetic and structural chemistry ofmetalborylcomplexeshasgrownalongwithcatalyticapplicationsi nwhich metal borylcomplexes are key intermediates. Likewise, the importance of metal borane -complexes as intermediates in many catalytic reactions has only recently been recognized [12], and thisarea is now a rapidly expanding one. 232 pp. Englisch. N� de ref. del art�culo: 9783642097393

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Contemporary Metal Boron Chemistry I : Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides

Zhenyang Lin

Publicado por Springer Berlin Heidelberg (2010)

ISBN 10: 3642097391 ISBN 13: 9783642097393

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Descripci�n Taschenbuch. Condici�n: Neu. Druck auf Anfrage Neuware - Printed after ordering - The eld of metal boron chemistry has been an especially active one since the 1960s. Much of the early work centered on the synthesis and structural characterization of polyhedral metallaborane and metallacarborane clusters, which will not be discussed in the current Volume. However, early work on metal boryl complexes by N�th et al. also appeared during this period, - thoughthe rstsimple metalborylcomplexestobestructurallycharacterized bysingle-crystalX-raydiffractionwerenotreporteduntil1990(indeed,crystal structuresofiridiumhydridoborylcomplexeswerereportednearlysimulta- ouslybyBaker,Marder,etal. [1]andbyMerolaetal. [2]),andthisnewinterest in the area arose speci cally as a result of the report by N�th et al. [3] on the rhodium-catalyzed hydroborationof alkenes using catecholborane. Although there had been previous reports of metal-catalyzed hydroboration employing polyhedralboranesorcarboranesastheB Hsource[4], theseminal paper by N�th et al. in 1985 [3] marked the beginning of interest by the organic ch- istry community in the application of this reaction in organic synthesis [5]. Whatensuedwasaveryrapidincreaseinthenumberofmetalborylcomplexes to be synthesized and structurally characterized, along with studies of their reactivity,in conjunctionwithan equally rapid growthinthedevelopment of catalytichydroborationchemistry[5]anditsasymmetricversion[5e]. Thiswas followedbyawidevarietyofotherborylationreactionscatalyzedbytr ansition metals including diborations, silylborations, stannylborations, and thiabo- tions of unsaturated organic substrates [6], borylations of , -unsaturated carbonyl compounds [7], borylations of C halide bonds [8], and most - cently, borylations of C H bonds in alkenes, arenes, heteroarenes, and even alkanes[9,10]. TheC halideandC Hborylationchemistryhasbeendrivenby thedevelopment andbroadapplicationoftheSuzuki Miyaura cross-coupling reaction[11],whichisnowoneofthemainC Cbond-formingreactionsinthe arsenal of the organic chemist. Thus, the synthetic and structural chemistry ofmetalborylcomplexeshasgrownalongwithcatalyticapplicationsinwhich metal borylcomplexes are key intermediates. Likewise, the importance of metal borane -complexes as intermediates in many catalytic reactions has only recently been recognized [12], and thisarea is now a rapidly expanding one. N� de ref. del art�culo: 9783642097393

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