Palladium(0)-Catalyzed Cross-Coupling and Cyclocondensations Reactions: Site-selective Palladium-Catalyzed Cross-Coupling Reactions and Synthesis of . of Hydrazone and Oxime Dianions

ISBN 10: 3639376498 / ISBN 13: 9783639376494
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Palladium(0)-Catalyzed Cross-Coupling and Cyclocondensations Reactions: Site-selective Palladium-Catalyzed Cross-Coupling Reactions and Synthesis of . of Hydrazone and Oxime Dianions. N° de ref. de la librería

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Sinopsis: The main part of this book is the efficient regioselective synthesis of functionalized heterocycles (furans, pyrroles, thiophenes, selenophenes) based on the palladium(0)-catalyzed cross-coupling and metal-halide exchanged reactions of brominated heterocycles. The study of the efficient methodologies (regioselectivities, optimization of condition including catalysts, solvent, temperature ?) to functionalize them to give a valuable synthetic procedure for the synthesis of pharmacologically relevant products and of useful intermediates for further synthetic transformations. These simple methodologies were applied to synthesize the sulfur- analogues of pyrrole natural product, such as ningaline A. The second part is oriented synthesis of N,O-heterocycles. The convenient approach to synthesized pyrazole-3-carboxylates and pyrazole-1,5- dicarboxylates by one-pot cyclization of hydrazone dianions with diethyl oxalate and 6-iodo- and 6- bromomethyl-5,6-dihydro-4H-1,2-oxazines by condensation of dilithiated acetophenone-oximes with allylbromide and subsequent regioselective iodine- or NBS-mediated cyclization were shown.

Biografía del autor: Dang Thanh Tung obtained his M.Sc. in chemistry at the Hanoi University of Sciences, Vietnam (2006) and his Dr. degree in the group of Prof. Peter Langer at the University of Rostock, Germany (2009). After studying with Prof. Rèmi Chauvin at Toulouse (2010), he joined the group of Prof. Valérie Heitz at the University of Strasbourg, France.

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Tung Thanh Dang
Editorial: VDM Verlag 2011-08-28 (2011)
ISBN 10: 3639376498 ISBN 13: 9783639376494
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Descripción VDM Verlag 2011-08-28, 2011. paperback. Estado de conservación: New. Nº de ref. de la librería 9783639376494

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Dang, Tung Thanh
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Descripción Estado de conservación: New. Publisher/Verlag: VDM Verlag Dr. Müller | Site-selective Palladium-Catalyzed Cross-Coupling Reactions and Synthesis of N,O-Heterocycles by Cyclocondensations of Hydrazone and Oxime Dianions | The main part of this book is the efficient regioselective synthesis of functionalized heterocycles (furans, pyrroles, thiophenes, selenophenes) based on the palladium(0)-catalyzed cross-coupling and metal-halide exchanged reactions of brominated heterocycles. The study of the efficient methodologies (regioselectivities, optimization of condition including catalysts, solvent, temperature ) to functionalize them to give a valuable synthetic procedure for the synthesis of pharmacologically relevant products and of useful intermediates for further synthetic transformations. These simple methodologies were applied to synthesize the sulfur- analogues of pyrrole natural product, such as ningaline A. The second part is oriented synthesis of N,O-heterocycles. The convenient approach to synthesized pyrazole-3-carboxylates and pyrazole-1,5- dicarboxylates by one-pot cyclization of hydrazone dianions with diethyl oxalate and 6-iodo- and 6- bromomethyl-5,6-dihydro-4H-1,2-oxazines by condensation of dilithiated acetophenone-oximes with allylbromide and subsequent regioselective iodine- or NBS-mediated cyclization were shown. | Format: Paperback | Language/Sprache: english | 160 pp. Nº de ref. de la librería K9783639376494

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Tung Thanh Dang
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Descripción VDM Verlag Aug 2011, 2011. Taschenbuch. Estado de conservación: Neu. 220x150x10 mm. Neuware - The main part of this book is the efficient regioselective synthesis of functionalized heterocycles (furans, pyrroles, thiophenes, selenophenes) based on the palladium(0)-catalyzed cross-coupling and metal-halide exchanged reactions of brominated heterocycles. The study of the efficient methodologies (regioselectivities, optimization of condition including catalysts, solvent, temperature ) to functionalize them to give a valuable synthetic procedure for the synthesis of pharmacologically relevant products and of useful intermediates for further synthetic transformations. These simple methodologies were applied to synthesize the sulfur- analogues of pyrrole natural product, such as ningaline A. The second part is oriented synthesis of N,O-heterocycles. The convenient approach to synthesized pyrazole-3-carboxylates and pyrazole-1,5- dicarboxylates by one-pot cyclization of hydrazone dianions with diethyl oxalate and 6-iodo- and 6- bromomethyl-5,6-dihydro-4H-1,2-oxazines by condensation of dilithiated acetophenone-oximes with allylbromide and subsequent regioselective iodine- or NBS-mediated cyclization were shown. 160 pp. Englisch. Nº de ref. de la librería 9783639376494

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Descripción VDM Verlag Aug 2011, 2011. Taschenbuch. Estado de conservación: Neu. 220x150x10 mm. This item is printed on demand - Print on Demand Neuware - The main part of this book is the efficient regioselective synthesis of functionalized heterocycles (furans, pyrroles, thiophenes, selenophenes) based on the palladium(0)-catalyzed cross-coupling and metal-halide exchanged reactions of brominated heterocycles. The study of the efficient methodologies (regioselectivities, optimization of condition including catalysts, solvent, temperature ) to functionalize them to give a valuable synthetic procedure for the synthesis of pharmacologically relevant products and of useful intermediates for further synthetic transformations. These simple methodologies were applied to synthesize the sulfur- analogues of pyrrole natural product, such as ningaline A. The second part is oriented synthesis of N,O-heterocycles. The convenient approach to synthesized pyrazole-3-carboxylates and pyrazole-1,5- dicarboxylates by one-pot cyclization of hydrazone dianions with diethyl oxalate and 6-iodo- and 6- bromomethyl-5,6-dihydro-4H-1,2-oxazines by condensation of dilithiated acetophenone-oximes with allylbromide and subsequent regioselective iodine- or NBS-mediated cyclization were shown. 160 pp. Englisch. Nº de ref. de la librería 9783639376494

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Tung Thanh Dang
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Descripción VDM Verlag Aug 2011, 2011. Taschenbuch. Estado de conservación: Neu. 220x150x10 mm. Neuware - The main part of this book is the efficient regioselective synthesis of functionalized heterocycles (furans, pyrroles, thiophenes, selenophenes) based on the palladium(0)-catalyzed cross-coupling and metal-halide exchanged reactions of brominated heterocycles. The study of the efficient methodologies (regioselectivities, optimization of condition including catalysts, solvent, temperature ) to functionalize them to give a valuable synthetic procedure for the synthesis of pharmacologically relevant products and of useful intermediates for further synthetic transformations. These simple methodologies were applied to synthesize the sulfur- analogues of pyrrole natural product, such as ningaline A. The second part is oriented synthesis of N,O-heterocycles. The convenient approach to synthesized pyrazole-3-carboxylates and pyrazole-1,5- dicarboxylates by one-pot cyclization of hydrazone dianions with diethyl oxalate and 6-iodo- and 6- bromomethyl-5,6-dihydro-4H-1,2-oxazines by condensation of dilithiated acetophenone-oximes with allylbromide and subsequent regioselective iodine- or NBS-mediated cyclization were shown. 160 pp. Englisch. Nº de ref. de la librería 9783639376494

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Descripción VDM Verlag, Germany, 2011. Paperback. Estado de conservación: New. 220 x 150 mm. Language: English . Brand New Book. The main part of this book is the efficient regioselective synthesis of functionalized heterocycles (furans, pyrroles, thiophenes, selenophenes) based on the palladium(0)-catalyzed cross-coupling and metal-halide exchanged reactions of brominated heterocycles. The study of the efficient methodologies (regioselectivities, optimization of condition including catalysts, solvent, temperature .) to functionalize them to give a valuable synthetic procedure for the synthesis of pharmacologically relevant products and of useful intermediates for further synthetic transformations. These simple methodologies were applied to synthesize the sulfur- analogues of pyrrole natural product, such as ningaline A. The second part is oriented synthesis of N, O-heterocycles. The convenient approach to synthesized pyrazole-3-carboxylates and pyrazole-1,5- dicarboxylates by one-pot cyclization of hydrazone dianions with diethyl oxalate and 6-iodo- and 6- bromomethyl-5,6-dihydro-4H-1,2-oxazines by condensation of dilithiated acetophenone-oximes with allylbromide and subsequent regioselective iodine- or NBS-mediated cyclization were shown. Nº de ref. de la librería KNV9783639376494

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