Nitroso: Functional Group, Organic Chemistry, Organic Compound, Substituent, Nitrosyl Chloride, Nitric Oxide

 
9786130921712: Nitroso: Functional Group, Organic Chemistry, Organic Compound, Substituent, Nitrosyl Chloride, Nitric Oxide
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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Nitroso refers to a functional group in organic chemistry which has the general formula RNO. Nitroso compounds are a class of organic compounds containing the nitroso functional group, R−N=O. Nitrosyls are molecules with the general formula RNO, where R represents an unspecified substituent. Nitroso and Nytrosyl are identical, but first name is used in organic chemistry, second one in inorganic chemistry. A common example is nitrosyl chloride, NOCl (although its structure is better represented ONCl). Nitrosyl also refers to the discrete molecule nitric oxide, NO. Nitric oxide is a stable radical, having an unpaired electron. Nitric oxide can serve as a ligand in complexes. The resulting complexes are called metal nitrosyls, and can bond to a metal atom in two distinct modes: as NO+ and as NO−. NO+ coordinates linearly, the M−N−O angle being 180°, whereas NO− forms a bent geometry, with an M−N−O angle of approximately 120°.

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