Interest in the transition metal oxides with perovskite related structures goes back to the 1950s when the sodium tungsten bronzes NaxWO3 were shown to be metallic [1 ], the system Lal_xSr~MnO3 was found to contain a ferromagnetic conductive phase [2], and La0.sSr0.sCoO3 was reported to be a ferromagnetic metal, but with a peculiar magnetization of 1.5 #a/Co atom [3]. Stoichiometric oxide perovskites have the generic formula AMO3 in which the A site is at the center of a simple cubic array of M sites; the oxide ions form (180 ° 4)) M O M bridges to give an MO3 array of corner shared MO6/2 octahedra and the larger A cations have twelvefold oxygen coordination. Mismatch between the A O and M O equilibrium bond lengths introduces internal stresses. A compressive stress on the MO3 array is accommodated by a lowering of the M O M bond angle from 180 ° to (180 ° 4)); a tensile stress on the M O M bonds is accommodated by the formation of hexagonal polytypes [4].
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Interest in the transition metal oxides with perovskite related structures goes back to the 1950s when the sodium tungsten bronzes NaxWO3 were shown to be metallic [1 ], the system Lal_xSr~MnO3 was found to contain a ferromagnetic conductive phase [2], and La0.sSr0.sCoO3 was reported to be a ferromagnetic metal, but with a peculiar magnetization of 1.5 #a/Co atom [3]. Stoichiometric oxide perovskites have the generic formula AMO3 in which the A site is at the center of a simple cubic array of M sites; the oxide ions form (180 ° 4)) M O M bridges to give an MO3 array of corner shared MO6/2 octahedra and the larger A cations have twelvefold oxygen coordination. Mismatch between the A O and M O equilibrium bond lengths introduces internal stresses. A compressive stress on the MO3 array is accommodated by a lowering of the M O M bond angle from 180 ° to (180 ° 4)); a tensile stress on the M O M bonds is accommodated by the formation of hexagonal polytypes [4].
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Condición: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. This series presents critical reviews of the present position and future trends in modern chemical researchShort and concise reports on chemistry, each written by the world s renowned experts. Still valid and useful after 5 or 10 years. More information. Nº de ref. del artículo: 4898248
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Buch. Condición: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Interest in the transition metal oxides with perovskite related structures goes back to the 1950s when the sodium tungsten bronzes NaxWO3 were shown to be metallic [1 ], the system Lal_xSr~MnO3 was found to contain a ferromagnetic conductive phase [2], and La0.sSr0.sCoO3 was reported to be a ferromagnetic metal, but with a peculiar magnetization of 1.5 #a/Co atom [3]. Stoichiometric oxide perovskites have the generic formula AMO3 in which the A site is at the center of a simple cubic array of M sites; the oxide ions form (180 ° 4)) M O M bridges to give an MO3 array of corner shared MO6/2 octahedra and the larger A cations have twelvefold oxygen coordination. Mismatch between the A O and M O equilibrium bond lengths introduces internal stresses. A compressive stress on the MO3 array is accommodated by a lowering of the M O M bond angle from 180 ° to (180 ° 4)); a tensile stress on the M O M bonds is accommodated by the formation of hexagonal polytypes [4]. 256 pp. Englisch. Nº de ref. del artículo: 9783540675228
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Buch. Condición: Neu. Localized to Itinerant Electronic Transition in Perovskite Oxides | John B. Goodenough | Buch | xii | Englisch | 2001 | Springer-Verlag GmbH | EAN 9783540675228 | Verantwortliche Person für die EU: Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg, juergen[dot]hartmann[at]springer[dot]com | Anbieter: preigu Print on Demand. Nº de ref. del artículo: 105096852
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Buch. Condición: Neu. Neuware -Interest in the transition metal oxides with perovskite related structures goes back to the 1950s when the sodium tungsten bronzes NaxWO3 were shown to be metallic [1 ], the system Lal_xSr~MnO3 was found to contain a ferromagnetic conductive phase [2], and La0.sSr0.sCoO3 was reported to be a ferromagnetic metal, but with a peculiar magnetization of 1.5 #a/Co atom [3]. Stoichiometric oxide perovskites have the generic formula AMO3 in which the A site is at the center of a simple cubic array of M sites; the oxide ions form (180 ° 4)) M O M bridges to give an MO3 array of corner shared MO6/2 octahedra and the larger A cations have twelvefold oxygen coordination. Mismatch between the A O and M O equilibrium bond lengths introduces internal stresses. A compressive stress on the MO3 array is accommodated by a lowering of the M O M bond angle from 180 ° to (180 ° 4)); a tensile stress on the M O M bonds is accommodated by the formation of hexagonal polytypes [4].Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 256 pp. Englisch. Nº de ref. del artículo: 9783540675228
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Buch. Condición: Neu. Druck auf Anfrage Neuware - Printed after ordering - Interest in the transition metal oxides with perovskite related structures goes back to the 1950s when the sodium tungsten bronzes NaxWO3 were shown to be metallic [1 ], the system Lal_xSr~MnO3 was found to contain a ferromagnetic conductive phase [2], and La0.sSr0.sCoO3 was reported to be a ferromagnetic metal, but with a peculiar magnetization of 1.5 #a/Co atom [3]. Stoichiometric oxide perovskites have the generic formula AMO3 in which the A site is at the center of a simple cubic array of M sites; the oxide ions form (180 ° 4)) M O M bridges to give an MO3 array of corner shared MO6/2 octahedra and the larger A cations have twelvefold oxygen coordination. Mismatch between the A O and M O equilibrium bond lengths introduces internal stresses. A compressive stress on the MO3 array is accommodated by a lowering of the M O M bond angle from 180 ° to (180 ° 4)); a tensile stress on the M O M bonds is accommodated by the formation of hexagonal polytypes [4]. Nº de ref. del artículo: 9783540675228
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