Photoinitiators for Polymer Synthesis: Scope, Reactivity, and Efficiency

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9783527332106: Photoinitiators for Polymer Synthesis: Scope, Reactivity, and Efficiency
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PHOTOINITIATING SYSTEMS FOR POLYMERIZATION REACTIONS ARE LARGELY ENCOUNTERED IN A VARIETY OF TRADITIONAL AND HIGH–TECH SECTORS, SUCH AS RADIATION CURING, (LASER) IMAGING, (MICRO)ELECTRONICS, OPTICS, AND MEDICINE. THIS BOOK EXTENSIVELY COVERS RADICAL AND NONRADICAL PHOTOINITIATING SYSTEMS AND IS DIVIDED INTO FOUR PARTS: * BASIC PRINCIPLES IN PHOTOPOLYMERIZATION REACTIONS * RADICAL PHOTOINITIATING SYSTEMS * NONRADICAL PHOTOINITIATING SYSTEMS * REACTIVITY OF THE PHOTOINITIATING SYSTEM THE FOUR PARTS PRESENT THE BASIC CONCEPTS OF PHOTOPOLYMERIZATION REACTIONS, REVIEW ALL OF THE AVAILABLE PHOTOINITIATING SYSTEMS AND DELIVER A THOROUGH DESCRIPTION OF THE ENCOUNTERED MECHANISMS. A LARGE AMOUNT OF EXPERIMENTAL AND THEORETICAL DATA HAS BEEN COLLECTED HEREIN. THIS BOOK ALLOWS THE READER TO GAIN A CLEAR UNDERSTANDING BY PROVIDING A GENERAL DISCUSSION OF THE PHOTOCHEMISTRY AND CHEMISTRY INVOLVED. THE MOST RECENT AND EXCITING DEVELOPMENTS, AS WELL AS THE PROMISING PROSPECTS FOR NEW APPLICATIONS, ARE OUTLINED.

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Photoinitiating systems for polymerization reactions are largely encountered in a variety of traditional and high-tech sectors, such as radiation curing, (laser) imaging, (micro)electronics, optics, and medicine. This book extensively covers radical and nonradical photoinitiating systems and is divided into four parts: Basic principles in photopolymerization reactions Radical photoinitiating systems Nonradical photoinitiating systems Reactivity of the photoinitiating system The four parts present the basic concepts of photopolymerization reactions, review all of the available photoinitiating systems and deliver a thorough description of the encountered mechanisms. A large amount of experimental and theoretical data has been collected herein. This book allows the reader to gain a clear understanding by providing a general discussion of the photochemistry and chemistry involved. The most recent and exciting developments, as well as the promising prospects for new applications, are outlined.

Biografía del autor:

Jean-Pierre Fouassier was a Professor of Physical Chemistry at the University of Haute Alsace, Mulhouse until October 2011. He was Head of a University/CNRS Laboratory, a Member of the Organizing Committees of many International Conferences, a Director of the Ecole Nationale Superieure de Chimie de Mulhouse and a Member of the French National University Council. His research interests focused both on the excited-state processes in photoinitiatiors and photosensitizers and their application to photopolymerization reactions in various areas. He has published a total of around 600 research articles, book chapters, review papers, technical papers, proceedings, and patents, as well as authoring one book, one technical report and editing 6 books (14 volumes). Jacques Lalevee is a Professor of Physical Chemistry at the University of Haute Alsace, Mulhouse. His research interests are focused on free-radical chemistry and the design of efficient systems for photopolymerization processes. He has published a total of around 160 research articles, technical papers, proceedings, patents, review papers, and book chapters. He is also a Member of the Institut Universitaire de France (Paris).

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Jean-Pierre Fouassier (author), Jacques Lalevée (author)
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J.P. Fouassier (formerly University of Haute Alsace, Mulhouse, France); Jacques Lalevée (University of Haute Alsace, Mulhouse, Frace)
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Descripción Condición: New. Publisher/Verlag: Wiley-VCH | Scope, Reactivity and Efficiency | This handbook covers radical and non-radical photoinitiating systems and describes the basic principles and applications of photopolymerization reactions within the fields of polymer and materials science. The book provides a complete survey of the respective photoinitiators and a thorough description of the mechanisms involved. | Photoinitiating systems for polymerization reactions are largely encountered in a variety of traditional and high-tech sectors, such as radiation curing, (laser) imaging, (micro)electronics, optics, and medicine.This book extensively covers radical and nonradical photoinitiating systems and is divided into four parts:Basic principles in photopolymerization reactionsRadical photoinitiating systemsNonradical photoinitiating systemsReactivity of the photoinitiating systemThe four parts present the basic concepts of photopolymerization reactions, review all of the available photoinitiating systems and deliver athorough description of the encountered mechanisms. A large amount of experimental and theoretical data has been collected herein. Thisbook allows the reader to gain a clear understanding by providing a general discussion of the photochemistry and chemistry involved.The most recent and exciting developments, as well as the promising prospects for new applications, are outlined. | INTRODUCTIONPART I: Basic Principles and Applications of Photopolymerization ReactionsPHOTOPOLYMERIZATION AND PHOTO-CROSS-LINKING LIGHT SOURCESElectromagnetic RadiationCharacteristics of a Light SourceConventional and Unconventional Light SourcesEXPERIMENTAL DEVICES AND EXAMPLES OF APPLICATIONSUV Curing Area: Coatings, Inks, Varnishes, Paints, and AdhesivesConventional Printing PlatesManufacture of Objects and CompositesStereolithographyApplications in MicroelectronicsLaser Direct ImagingComputer-to-Plate TechnologyHolographyOpticsMedical ApplicationsFabrication of Nano-Objects through a Two-Photon Absorption PolymerizationPhotopolymerization Using Near-Field Optical TechniquesSearch for New Properties and New End UsesPhotopolymerization and NanotechnologySearch for a Green ChemistryPHOTOPOLYMERIZATION REACTIONSEncountered Reactions, Media, and Experimental ConditionsTypical Characteristics of Selected Photopolymerization ReactionsTwo-Photon Absorption-Induced PolymerizationRemote Curing: Photopolymerization without LightPhotoactivated Hydrosilylation ReactionsPHOTOSENSITIVE SYSTEMSGeneral PropertiesAbsorption of Light by a MoleculeJablonski's DiagramKinetics of the Excited State ProcessesPhotoinitiator and PhotosensitizerAbsorption of a Photosensitive SystemInitiation Step of a Photoinduced PolymerizationReactivity of a Photosensitive SystemAPPROACH OF THE PHOTOCHEMICAL AND CHEMICAL REACTIVITYAnalysis of the Excited-State ProcessesQuantum Mechanical CalculationsCleavage ProcessHydrogen Transfer ProcessesEnergy TransferReactivity of RadicalsEFFICIENCY OF A PHOTOPOLYMERIZATION REACTIONKinetic LawsMonitoring the Photopolymerization ReactionEfficiency versus ReactivityAbsorption of Light by a PigmentOxygen InhibitionAbsorption of Light StabilizersRole of the EnvironmentPART II: Radical Photoinitiating SystemsONE-COMPONENT PHOTOINITIATING SYSTEMSBenzoyl-Chromophore-Based PhotoinitiatorsSubstituted Benzoyl-Chromophore-Based PhotoinitiatorsHydroxy Alkyl Heterocyclic KetonesHydroxy Alkyl Conjugated KetonesBenzophenone- and Thioxanthone-Moiety-Based Cleavable SystemsBenzoyl Phosphine Oxide DerivativesPhosphine Oxide DerivativesTrichloromethyl TriazinesBiradical-Generating KetonesPeroxidesDiketonesAzides and Aromatic Bis-AzidesAzo DerivativesDisulfide DerivativesDisilane DerivativesDiselenide and Diphenylditelluride DerivativesDigermane and Distannane DerivativesCarbon - Germanium Cleavable-Bond-Based DerivativesCarbon - Silicon and Germanium 'Silicon Cleavable' Bond-Based DerivativesSilicon Chemistry and Conventional Cleavable PhotoinitiatorsSulfur - C. Nº de ref. del artículo: K9783527332106

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J. P. Fouassier
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Descripción Wiley VCH Verlag Gmbh Jul 2012, 2012. Buch. Condición: Neu. Neuware - Photoinitiating systems for polymerization reactions are largely encountered in a variety of traditional and high-tech sectors, such as radiation curing, (laser) imaging, (micro)electronics, optics, and medicine. This book extensively covers radical and nonradical photoinitiating systems and is divided into four parts: Basic principles in photopolymerization reactions Radical photoinitiating systems Nonradical photoinitiating systems Reactivity of the photoinitiating system The four parts present the basic concepts of photopolymerization reactions, review all of the available photoinitiating systems and deliver a thorough description of the encountered mechanisms. A large amount of experimental and theoretical data has been collected herein. This book allows the reader to gain a clear understanding by providing a general discussion of the photochemistry and chemistry involved. The most recent and exciting developments, as well as the promising prospects for new applications, are outlined. 476 pp. Englisch. Nº de ref. del artículo: 9783527332106

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J. P. Fouassier
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Descripción Wiley VCH Verlag Gmbh Jul 2012, 2012. Buch. Condición: Neu. Neuware - Photoinitiating systems for polymerization reactions are largely encountered in a variety of traditional and high-tech sectors, such as radiation curing, (laser) imaging, (micro)electronics, optics, and medicine. This book extensively covers radical and nonradical photoinitiating systems and is divided into four parts: Basic principles in photopolymerization reactions Radical photoinitiating systems Nonradical photoinitiating systems Reactivity of the photoinitiating system The four parts present the basic concepts of photopolymerization reactions, review all of the available photoinitiating systems and deliver a thorough description of the encountered mechanisms. A large amount of experimental and theoretical data has been collected herein. This book allows the reader to gain a clear understanding by providing a general discussion of the photochemistry and chemistry involved. The most recent and exciting developments, as well as the promising prospects for new applications, are outlined. 476 pp. Englisch. Nº de ref. del artículo: 9783527332106

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J. P. Fouassier
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Descripción Wiley VCH Verlag Gmbh Jul 2012, 2012. Buch. Condición: Neu. Neuware - Photoinitiating systems for polymerization reactions are largely encountered in a variety of traditional and high-tech sectors, such as radiation curing, (laser) imaging, (micro)electronics, optics, and medicine. This book extensively covers radical and nonradical photoinitiating systems and is divided into four parts: Basic principles in photopolymerization reactions Radical photoinitiating systems Nonradical photoinitiating systems Reactivity of the photoinitiating system The four parts present the basic concepts of photopolymerization reactions, review all of the available photoinitiating systems and deliver a thorough description of the encountered mechanisms. A large amount of experimental and theoretical data has been collected herein. This book allows the reader to gain a clear understanding by providing a general discussion of the photochemistry and chemistry involved. The most recent and exciting developments, as well as the promising prospects for new applications, are outlined. 476 pp. Englisch. Nº de ref. del artículo: 9783527332106

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J. P. Fouassier
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Descripción Wiley VCH Verlag Gmbh Jul 2012, 2012. Buch. Condición: Neu. Neuware - Photoinitiating systems for polymerization reactions are largely encountered in a variety of traditional and high-tech sectors, such as radiation curing, (laser) imaging, (micro)electronics, optics, and medicine. This book extensively covers radical and nonradical photoinitiating systems and is divided into four parts: Basic principles in photopolymerization reactions Radical photoinitiating systems Nonradical photoinitiating systems Reactivity of the photoinitiating system The four parts present the basic concepts of photopolymerization reactions, review all of the available photoinitiating systems and deliver a thorough description of the encountered mechanisms. A large amount of experimental and theoretical data has been collected herein. This book allows the reader to gain a clear understanding by providing a general discussion of the photochemistry and chemistry involved. The most recent and exciting developments, as well as the promising prospects for new applications, are outlined. 476 pp. Englisch. Nº de ref. del artículo: 9783527332106

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