Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications

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9780306457364: Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications

The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde­ pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc­ ture of electrolyte solutions into the model of a metal/solution interface, by en­ visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti­ cians have introduced a number of new parameters of which people were not aware 50 years ago.

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Review:

`It is an excellent resource in that it provides a very comprehensive and in depth coverage of supercapacitor technology.'
IEEE Electrical Insulation Magazine, 18:2 (2002)

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Descripción Springer Science+Business Media, United States, 1999. Hardback. Estado de conservación: New. 1999 ed.. Language: English . This book usually ship within 10-15 business days and we will endeavor to dispatch orders quicker than this where possible. Brand New Book. The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde- pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc- ture of electrolyte solutions into the model of a metal/solution interface, by en- visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti- cians have introduced a number of new parameters of which people were not aware 50 years ago. Nº de ref. de la librería LIE9780306457364

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ELECTROCHEMICAL SUPERCAPACITORS. SCIENTIFIC FUNDAMENTALS AND TECHNOLOGICAL APPLICATIONS -
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Descripción Springer, 1999. Hardback. Estado de conservación: NEW. 9780306457364 This listing is a new book, a title currently in-print which we order directly and immediately from the publisher. Nº de ref. de la librería HTANDREE0270314

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Descripción Springer, 2017. Hardcover. Estado de conservación: New. This item is printed on demand. Nº de ref. de la librería P110306457369

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Descripción Springer, 1999. Hardcover. Estado de conservación: New. book. Nº de ref. de la librería 0306457369

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Descripción Springer Science+Business Media, United States, 1999. Hardback. Estado de conservación: New. 1999 ed.. Language: English . Brand New Book ***** Print on Demand *****.The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde- pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc- ture of electrolyte solutions into the model of a metal/solution interface, by en- visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti- cians have introduced a number of new parameters of which people were not aware 50 years ago. Nº de ref. de la librería APC9780306457364

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B. E. Conway
Editorial: Springer Science+Business Media, United States (1999)
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Descripción Springer Science+Business Media, United States, 1999. Hardback. Estado de conservación: New. 1999 ed.. Language: English . Brand New Book ***** Print on Demand *****. The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde- pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as point charges as in the Gouy-Chapman treatment, and let the center of the ion charges reside at some distance from the metal surface while the distribution was still governed by the Gouy-Chapman view. Finally, in 1947, D. C. Grahame transferred the knowledge of the struc- ture of electrolyte solutions into the model of a metal/solution interface, by en- visaging different planes of closest approach to the electrode surface depending on whether an ion is solvated or interacts directly with the solid wall. Thus, the Gouy-Chapman-Stern-Grahame model of the so-called electrical double layer was born, a model that is still qualitatively accepted, although theoreti- cians have introduced a number of new parameters of which people were not aware 50 years ago. Nº de ref. de la librería APC9780306457364

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B. E. Conway
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Descripción Springer, 1999. Estado de conservación: New. This item is printed on demand for shipment within 3 working days. Nº de ref. de la librería LP9780306457364

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